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教授/研究员
- 教授/研究员
- 副教授/高级实验师
- 讲师/实验师
- 退休/已工作过的职工
姓名: 姚昌广
性别: 男
职称: 特聘教授
学位: 博士
专业:化学工程与工艺,高分子化学与物理
研究方向:废旧塑料回收利用,生物基/可降解/可循环高分子制备,过渡金属催化剂设计,聚合新方法开发
教育工作经历
2020.01年至今:yl23455永利官网,特聘教授,硕士生导师,从事教学、科研工作。
2015.12~2019.12: King Abdullah University of Science and Technology, 博士后(合作导师:Kuo-Wei Huang教授)
2009.09~2015.07: 中国科学院长春应用化学研究所,获博士学位(导师:崔冬梅研究员)
2005.09~2009.07: 陕西师范大学,获学士学位
教学简介
本科生课程:《有机化学》、《有机化学实验》、《化工生产实习》
科研简介
主要从事过渡金属催化剂设计及其催化废旧塑料降解回收、生物基/可循环/可降解高分子制备、惰性分子活化以及绿色聚合方法开发等方面的研究。已在Angew. Chem. Int. Ed., Green. Chem., Macromolecules, Chem. Commun., Polym. Chem.等国际知名期刊发表论文三十多篇,授权中国发明专利5项,PCT国际专利1项。
科研项目
1. 国家自然科学基金:“廉价金属-配体协同”催化呋喃类单体脱氢缩聚合成生物基聚酯 (22061027),2021-2024年,40万元
2. 国家自然科学基金:过渡金属配合物催化二醇/二硫醇脱氢缩聚制备化学可回收聚硫酯 (22261034),2023-2026年,33万元
3. 江西省自然科学基金:生物基可化学循环芳香族聚酯的制备及其氢化解聚研究,2024-2026年,20万元
4. 江西省自然科学基金:共价有机框架负载钌催化材料的构筑及其催化废弃聚酯氢化解聚研究 (20224BAB203023),2023-2025年,10万元
社会兼职
担任Green. Chem., Macromolecules, Chem. Commun., Polym. Chem.等期刊审稿人
获奖情况
代表性论文及专利
1. Changguang Yao, Tonghuan Zhang, Théo P. Gonçalves and Kuo-Wei Huang*. “Selective Benzylic Csp3–H Bond Activations Mediated by a Phosphorus–Nitrogen PN3P-Nickel Complex”. Chem. Commun. 2022, 58, 1593-1596.
2. Changguang Yao, Xiufang Wang and Kuo-Wei Huang*. “Nitrogen Atom Transfer Mediated by a New PN3P-Pincer Nickel Core via a Putative Nitrido Nickel Intermediate”. Chem. Commun. 2018,54, 3940–3943.
3. Changguang Yao, Fei Lin, Meiyan Wang, Dongtao Liu, Bo Liu, Na Liu, Zichuan Wang, Shiyu Long, Chunji Wu* and Dongmei Cui*. “Highly Syndioselective 3,4-Trans Polymerization of (E)-1-(4-Methylphenyl)-1,3-butadiene by Fluorenyl N-Heterocyclic Carbene Ligated Lutetium Bis(alkyl) Precursor”. Macromolecules 2015, 48, 1999–2005.
4. Changguang Yao, Na Liu, Shiyu Long, Chunji Wu and Dongmei Cui*. “Highly cis-1,4-Selective Coordination Polymerization of Polar 2-(4-Methoxyphenyl)-1,3-Butadiene and Copolymerization with Isoprene Using a β-Diketiminato Yttrium Bis(alkyl) Complex”. Polym. Chem. 2016, 7, 1264–1270.
5. Wei-Ming Xu, Yuan-Dong Yu, Meng-Xiang Ma, Hui-Du Xu, Rui-Qin Wang, Yu-Peng Pan, Ke-Qin Wu; Wei-Ran Yang*, Chang-Guang Yao*. “Green Synthesis of Chemically Recyclable Polyesters via Dehydrogenative Copolymerization of Diols”. Chinese J. Polym. Sci. 2023, 41, 1206-1214.
6. Changguang Yao, Priyanka Chakraborty, Emanuele Aresu, Huaifeng Li, Chao Guan, Chunhui Zhou, Lan-Chang Liang* and Kuo-Wei Huang*. “Monomeric Nickel Hydroxide Stabilized by a Sterically Demanding Phosphorus-Nitrogen PN3P-pincer Ligand: Synthesis, Reactivity and Catalysis”. Dalton Trans., 2018, 47, 16057–16065.
7. Changguang Yao, Tonghuan Zhang, Chunhui Zhou and Kuo-Wei Huang*. “Interrogating the Steric Outcome During H2 Heterolysis: In-Plane Steric Effects in the Regioselective Protonation of the PN3P-Pincer Ligand”. Dalton Trans., 2019, 48, 12817–12821.
8. Changguang Yao, Dongtao Liu, Ping Li, Chunji Wu, Shihui Li, Bo Liu and Dongmei Cui*. “Highly 3,4-Selective Living Polymerization of Isoprene and Copolymerization with ε-Caprolactone by an Amidino N-heterocyclic Carbene Ligated Lutetium Bis(alkyl) Complex”. Organometallics 2014, 33, 684–691.
9. Changguang Yao, Chunji Wu, Baoli Wang and Dongmei Cui*. “Copolymerization of Ethylene with 1-Hexene and 1-Octene Catalyzed by Fluorenyl N-Heterocyclic Carbene Ligated Rare-Earth Metal Precursors”. Organometallics 2013, 32, 2204–2209.
10. Changguang Yao, Hongyan Xie, Dongmei Cui*. Highly 3,4-selective living polymerization of 2-phenyl-1,3-butadiene with amidino N-heterocyclic carbene ligated rare-earth metal bis(alkyl) complexes. RSC Adv. 2015, 5, 93507-93512.
11. 姚昌广,于元栋,许慧都,杨维冉:一种香草醛基聚酯的制备方法(ZL 2022 1 0097450.1)
12. 崔冬梅,姚昌广,吴春姬,刘波,亚历山大·特里弗诺夫:稀土催化剂组合及其用于异戊二烯类化合物的3, 4-聚合(ZL 2013 1 0689037.5)
13. 崔冬梅,姚昌广,吴春姬,刘波:2-芳基-1, 3丁二烯3, 4-聚合物及其制备方法(ZL 2015 1 0224201.4)
14. 崔冬梅,姚昌广,刘东涛,吴春姬:2-芳基-1, 3丁二烯顺-1, 4-聚合物及其制备方法(ZL 2015 1 0224184.4)
15. 崔冬梅,吴春姬,姚昌广:茂金属配合物及其制备方法、催化剂组合物(ZL 2013 1 0478190.3, US 9896519 B2, EP 3056505 B1, JP 6302565 B2)